The recently synthesized Engelhard titanosilicate (ETS-10) represents
a material which contains in the structure well defined atomic ... O-T
i-O-Ti-O ... quantum wires embedded in a highly insulating siliceous m
atrix. We report and discuss the UV-Vis spectrum of this material and
compare the experimentally determined optical band gap with the result
s predicted by simple modeling of a titanium oxide semiconductor wire
unidimensionally confined by an infinite potential barrier. (C) 1997 A
merican Institute of Physics.