A very small amount of pre-deposited C on a Si substrate causes island
formation after epitaxial growth of less than 2 monolayers Ge. These
C-induced Ge dots can be as small as 10 nm in lateral size and 1 nm in
height. Their areal density is 10(11) cm(-2). Intense photoluminescen
ce signal from these small Ge quantum dots is observed reaching a maxi
mum for 2.1+/-0.3 monolayers of Ge. In the initial stages of island fo
rmation, the optical transition of the wetting layer is blue-shifted b
y strain compensation effects. We propose spatially indirect mechanism
s of radiative recombination between electrons confined in the underly
ing wetting layer and holes confined in the Ge islands. (C) 1997 Ameri
can Institute of Physics.