Tj. Millar et E. Herbst, A NEW CHEMICAL-MODEL OF THE CIRCUMSTELLAR ENVELOPE SURROUNDING IRC+10216, Astronomy and astrophysics, 288(2), 1994, pp. 561-571
A new chemical model of the circumstellar envelope surrounding the car
bon-rich star IRC+10216 has been developed. This model incorporates a
variety of newly measured rapid neutral-neutral reactions between carb
on atoms and hydrocarbons and between the radical CN and a variety of
stable neutral molecules. In addition, other neutral-neutral reactions
in the above two classes or involving atoms such as N or radicals suc
h as C(2n)H have been included with large rate coefficients although t
hey have not yet been studied in the laboratory. Unlike the interstell
ar case, where the inclusion of these neutral-neutral reactions destro
ys molecular complexity, our model results for IRC+10216 show that suf
ficient abundances of large hydrocarbon radicals and cyanpolyynes can
be produced to explain observations. We also discuss the formation of
H2CN and NH2CN, two potentially observable molecules in IRC+10216.