We report the first experimental observation of a gap-opening and chan
ges of the Fermi surface contours upon reconstruction of the W(001) su
rface. A gap Delta greater than or equal to 0.6 eV is found to form at
(X) over bar', a new surface Brillouin zone boundary along the <(Sigm
a)over bar> azimuth of the reconstructed (root 2 x root 2)R45 degrees
structure. The large gap and the Fermi surface contours of which the c
urvatures remain essentially unaltered through reconstruction suggest
that the reconstruction is driven primarily by a strong-coupling charg
e density wave mechanism. (C) 1997 Elsevier Science B.V.