T. Petrosky et I. Prigogine, THE EXTENSION OF CLASSICAL DYNAMICS FOR UNSTABLE HAMILTONIAN-SYSTEMS, Computers & mathematics with applications, 34(2-4), 1997, pp. 1-44
Classical dynamics can be formulated in terms of trajectories or in te
rms of statistical ensembles whose time evolution is described by the
Liouville equation. It is shown that for the class of large nonintegra
ble Poincare systems (LPS), the two descriptions are not equivalent. P
ractically all dynamical systems studied in statistical mechanics belo
ng to this class. The basic step is the extension of the Liouville ope
rator L-H outside the Hilbert space to functions singular in their Fou
rier transformation. This function space plays an important role in st
atistical mechanics as functions of the Hamiltonian, and therefore equ
ilibrium distribution functions belong to this class. Physically, thes
e functions correspond to situations characterized by ''persistent int
eractions'' as they are realized in macroscopic physics. Persistent in
teractions are introduced in contrast to ''transient interactions'' st
udied in quantum mechanics by the S-matrix approach (asymptotically fr
ee in and out states). The eigenvalue problem for the Liouville operat
or L-H is solved in this generalized function space for LPS. We obtain
a complex, irreducible spectral representation. Complex means that th
e eigenvalues are complex numbers, whose imaginary parts refer to the
various irreversible processes such as relaxation times, diffusion....
Irreducible means that these representations cannot be implemented by
trajectory theory. As the result, the dynamical group of evolution sp
lits into two semigroups. Moreover, the laws of classical dynamics tak
e a new form as they have to be formulated on the statistical level. T
hey express ''possibilities'' and no more ''certitudes''. Two examples
of typical classical systems, i.e., interacting particles and anharmo
nic lattices are studied.