High resolution optical spectra of four blue supergiants (HD148422 B0.
5 Ib; HD178487 B0.5 Ib; HD179407 B1 Ib, HD163522 B1 Ib) which lie with
in 4.5 kpc of the Galactic centre are presented. Careful differential
LTE model atmosphere analyses are used to quantify the differences in
photospheric metal abundances between these stars and MK spectral stan
dards in the solar neighborhood. A detailed non-LTE model atmosphere a
nalysis of one star (HD163522) confirms that the LTE differential abun
dances should be reliable, provided we use a comparison star with simi
lar atmospheric parameters. One star (HD148422; R-g = 4.5 kpc) has a c
hemical composition similar to normal nearby B-type stars while HD1784
87 (R-g = 4.1 kpc) shows a mild but consistent pattern of a metal enha
nced atmosphere (with elements up by 0.1-0.3 dex). The other two stars
HD163522 (R-g = 4.1 kpc) and HD179407 (R-g = 3.5 kpc) have significan
tly higher metal compositions than their standard comparison stars wit
h abundances enhanced by 0.3-0.40 dex and 0.20-0.5 dex respectively. A
ll of the stars lie outside the Galactic plane (with distances in the
range 0.5 < z < 1.4 kpc) and its is likely that they all have been eje
cted from the disk at an earlier point in their lifetime. Their radial
velocities are examined and we consider possible ejection mechanisms
which constrain their regions of origin in the Galactic disk. We compa
re our results with the sulphur and oxygen abundances expected from st
udies of H II regions (Shaver et al. 1983, Simpson et al 1995) and fin
d that for the metal rich stars, the studies are reasonably consistent
, given the uncertainties in the stellar formation sites. However meta
llicities of the other two stars are lower than those predicted from t
he H II regions. We find that other elements (Mg, Al, Si, S, Fe) follo
w enhancement patterns similar to oxygen, in contrast to both H II stu
dies which produce different abundance gradients for other metals. Thi
s paper, the first in a series, shows the potential of using early-typ
e stars to determine metal abundances in regions of low extinction tow
ard the Galactic centre, allowing an extension of the baseline for ste
llar abundance gradient studies.