HYDROFORMYLATION OF 1-HEXENE WITH THE USE OF CO(COOR)(2) AS THE CATALYST PRECURSOR

Authors
VIGRANENKO YT KATSNELSON MG
Citation
Yt. Vigranenko et Mg. Katsnelson, HYDROFORMYLATION OF 1-HEXENE WITH THE USE OF CO(COOR)(2) AS THE CATALYST PRECURSOR, Petroleum chemistry, 37(3), 1997, pp. 218-224
Citations number
13
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
37
Issue
3
Year of publication
1997
Pages
218 - 224
Database
ISI
SICI code
0965-5441(1997)37:3<218:HO1WTU>2.0.ZU;2-Y
Abstract
The use of Co(COOR)(2) as the catalyst precursor enables C6H13CHO alde hydes and C6H13CH2OH alcohols to be produced from 1-hexene and CO + H- 2 synthesis gas. The influence of the concentrations of the unsaturate d substrate and cobalt on the rate of the reaction has been establishe d. On the basis of the mechanisms of stages of activation of the catal yst precursor and hydroformylation, a kinetic equation has been derive d which takes account of the influence of the main parameters on the r ate of the reaction. (C) 1997 Elsevier Science Ltd. All rights reserve d.