WACKER OXIDATION OF OLEFINS IN THE PRESENCE OF PALLADIUM COMPLEXES BASED ON FUNCTIONALIZED POLYETHYLENE OXIDES AND BLOCK-COPOLYMERS OF ETHYLENE-OXIDE AND PROPYLENE-OXIDE

Authors
KARAKHANOV EA MAKSIMOV AL REDCHIN AS PREDEINA VV FILIPPOVA TY
Citation
Ea. Karakhanov et al., WACKER OXIDATION OF OLEFINS IN THE PRESENCE OF PALLADIUM COMPLEXES BASED ON FUNCTIONALIZED POLYETHYLENE OXIDES AND BLOCK-COPOLYMERS OF ETHYLENE-OXIDE AND PROPYLENE-OXIDE, Petroleum chemistry, 37(3), 1997, pp. 236-239
Citations number
8
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
37
Issue
3
Year of publication
1997
Pages
236 - 239
Database
ISI
SICI code
0965-5441(1997)37:3<236:WOOOIT>2.0.ZU;2-U
Abstract
A study has been made of the Wacker oxidation of 1-dodecene by air oxy gen in aqueous-organic media in the presence of macromolecular palladi um complexes based on iminodipropionitrile-functionalized ethylene oxi de and block copolymers of ethylene oxide and propylene oxide. Copper dichloride or benzoquinone was used as the cocatalyst. It was establis hed that the reaction proceeds selectively with high 2-dodecanone yiel ds. (C) 1997 Elsevier Science Ltd. All rights reserved.