CAPILLARY CHROMATOGRAPHY OF HYDROCARBONS AND THEIR DERIVATIVES - USE OF SULFUR-HEXAFLUORIDE AS THE CARRIER GAS

Authors
MALYUKOVA IV BEREZKIN VG KRAMERS K JANSEN HG
Citation
Iv. Malyukova et al., CAPILLARY CHROMATOGRAPHY OF HYDROCARBONS AND THEIR DERIVATIVES - USE OF SULFUR-HEXAFLUORIDE AS THE CARRIER GAS, Petroleum chemistry, 37(3), 1997, pp. 265-272
Citations number
11
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
37
Issue
3
Year of publication
1997
Pages
265 - 272
Database
ISI
SICI code
0965-5441(1997)37:3<265:CCOHAT>2.0.ZU;2-X
Abstract
A comparative study has been made of the dependence of the parameters of retention (capacity coefficient, relative retention, retention indi ces) of organic compounds on the average pressure of the carrier gas i n the column, with the use of helium and sulphur hexafluoride as the c arrier gases, and SE-30 and PEG-20 M as the stationary liquid phase, T he marked change in retention when helium is replaced with sulphur hex achloride as the carrier gas makes it possible to regard the carrier g as as a factor influencing the retention and separation of the compoun ds analysed. (C) 1997 Elsevier Science Ltd. All rights reserved.