C. Guran et al., PRECURSORS OF OXIDES WITH POTENTIAL SUPERCONDUCTIVITY .1. POLYNUCLEARCOMPLEXES IN THE LN-CU-BA-ETHANOLAMINE SYSTEM (LN=LA, CE), Revue Roumaine de Chimie, 42(4), 1997, pp. 289-295
The paper reports the synthesis of some new polynuclear complexes obta
ined in the Ln-Cu-(Ba)-TEA system (Ln = La, Ce, TEA = triethanolamine)
. These complexes were used as precursors for CuLa2O4 and LnBaCuO(7-de
lta)(Ln = La, Ce) mixed oxides and were characterized by elemental ana
lysis, spectroscopic analysis (electronic, IR, epr), X-ray powder diag
rams and thermal analysis.