STERICALLY LOADED INDENYL COMPLEXES OF ZIRCONIUM AND HAFNIUM

Authors
SCHMID C ALT HG MILIUS W
Citation
C. Schmid et al., STERICALLY LOADED INDENYL COMPLEXES OF ZIRCONIUM AND HAFNIUM, Journal of organometallic chemistry, 544(1), 1997, pp. 139-142
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
544
Issue
1
Year of publication
1997
Pages
139 - 142
Database
ISI
SICI code
0022-328X(1997)544:1<139:SLICOZ>2.0.ZU;2-Q
Abstract
The reaction of zirconocene dichloride, Cp2ZrCl2, and bis(indenyl) met al dichloride, Ind(2)MCl(2) (M = Zr, Hf), with one and two equivalents , respectively, of indenyl or fluorenyl lithium leads to sterically cr owded complexes with three or four potential pi-ligands (1: Cp2Zr(Ind) Cl; 2: Cp2Zr(Ind)(2); 3: Ind(3)ZrCl; 4: Ind(3)HfCl; 5: Ind(2)Zr(Flu)Cl ). Compound 4 was characterized by an X-ray structure analysis.