Yj. Wu et al., CYCLOMETALATION OF FERROCENYLIMINES .3. REGIOSELECTIVITY IN HG(II) CYCLOMETALATED COMPLEXES, Journal of organometallic chemistry, 543(1-2), 1997, pp. 63-70
The synthesis and mercuration of a series of Schiff bases 1'-benzoyl-1
-[(arylimino)phenylmethyl]ferrocene (aryl: a variety of substituted ph
enyls) have been studied. In all cases the mercuration occurred at the
2-position of the ferrocene ring. Oxygen --> mercury coordinated prod
ucts were not obtained. The X-ray crystal structure of ercurio-1-[((ph
enylimino)phenylmethyl)-1'-benzoyl] ferrocene 5c has been determined;
this crystallizes in the monoclinic, space group P2(1)/c with a = 10.1
68(3), b = 16.105(3), c = 15.463(4)Angstrom, beta = 103.61(2)degrees a
nd Z = 4. Refinement of atomic parameters gave an R factor of 0.038 (R
omega = 0.055) for 2440 unique reflections having I > 3 sigma(I). The
structure confirms the formation of a five-membered metallocycle on t
he ferrocene moiety. (C) 1997 Elsevier Science S.A.