SEQUENTIAL H-MIGRATION REACTIONS IN THE FORMATION OF [OS-3(MU(2)-H)(MU(2)-PHME)(CO)(10)] AND [OS-3(MU(2)-H)(2)(MU(3)-PME)(CO)(9)] DURING THE REACTION BETWEEN THE PHOSPHINIDENE COMPLEX [W(PME)(CO)(5)] AND [OS-3(MU(2)-H)(2)(CO)(10)]

Authors
AJULU FA MATHEY F NIXON JF
Citation
Fa. Ajulu et al., SEQUENTIAL H-MIGRATION REACTIONS IN THE FORMATION OF [OS-3(MU(2)-H)(MU(2)-PHME)(CO)(10)] AND [OS-3(MU(2)-H)(2)(MU(3)-PME)(CO)(9)] DURING THE REACTION BETWEEN THE PHOSPHINIDENE COMPLEX [W(PME)(CO)(5)] AND [OS-3(MU(2)-H)(2)(CO)(10)], Journal of organometallic chemistry, 543(1-2), 1997, pp. 245-247
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
543
Issue
1-2
Year of publication
1997
Pages
245 - 247
Database
ISI
SICI code
0022-328X(1997)543:1-2<245:SHRITF>2.0.ZU;2-V
Abstract
The transient phosphinidene complex [W(PMe)(CO)(5)] reacts with the un saturated [Os-3(mu(2)-H)(2)(CO)(10)] cluster to afford [Os-3(mu(2)- H) (mu(2)-PHMe)(CO)(10)] and subsequently [Os-3(mu(2)-H)(2)(mu(3)-PMe)(CO )(9)] via H-migration reactions involving both transfer from Os to P a nd from P to Os. (C) 1997 Elsevier Science S.A.