DETERMINATION OF STRUCTURAL DATA FROM MULTIPLE-QUANTUM MAGIC-ANGLE-SPINNING NMR EXPERIMENTS

Authors
Citation
Mj. Duer, DETERMINATION OF STRUCTURAL DATA FROM MULTIPLE-QUANTUM MAGIC-ANGLE-SPINNING NMR EXPERIMENTS, Chemical physics letters, 277(1-3), 1997, pp. 167-174
Citations number
31
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
277
Issue
1-3
Year of publication
1997
Pages
167 - 174
Database
ISI
SICI code
0009-2614(1997)277:1-3<167:DOSDFM>2.0.ZU;2-M
Abstract
It has recently been shown that multiple-quantum magic-angle spinning (MQMAS) NMR spectroscopy produces high-resolution spectra for half-int eger quadrupolar nuclei which suffer second-order quadrupole coupling. The present work shows how the effects of magnified dipole-dipole cou pling in MQMAS spectra can be analysed to produce quantitative structu ral data. (C) 1997 Elsevier Science B.V.