PHOSPHORUS YLIDE NIOBIUM COMPLEXES - SYNTHESIS AND CHARACTERIZATION OF THE FIRST ALPHA-KETO YLIDE COMPLEXES, [(NBCL3(YLIDE-O,N))(2)] AND [NBCL3(YLIDE-O,N)(RC-CR')] (YLIDE = -THIAZOLYLCARBONYL)METHYLENE]TRIPHENYLPHOSPHORANE, NOSC4H2CH-PPH3) - MOLECULAR-STRUCTURE OF [NBCL3(NOSC4H2CHPPH3-O,N)(PHC-CPR)] (PH = PHENYL, PR = PROPY)

Authors
DIEZBARRA E FERNANDEZBAEZA J KUBICKI MM LARASANCHEZ A OTERO A POUJAUD N TEJEDA J
Citation
E. Diezbarra et al., PHOSPHORUS YLIDE NIOBIUM COMPLEXES - SYNTHESIS AND CHARACTERIZATION OF THE FIRST ALPHA-KETO YLIDE COMPLEXES, [(NBCL3(YLIDE-O,N))(2)] AND [NBCL3(YLIDE-O,N)(RC-CR')] (YLIDE = -THIAZOLYLCARBONYL)METHYLENE]TRIPHENYLPHOSPHORANE, NOSC4H2CH-PPH3) - MOLECULAR-STRUCTURE OF [NBCL3(NOSC4H2CHPPH3-O,N)(PHC-CPR)] (PH = PHENYL, PR = PROPY), Journal of organometallic chemistry, 542(2), 1997, pp. 291-294
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
542
Issue
2
Year of publication
1997
Pages
291 - 294
Database
ISI
SICI code
0022-328X(1997)542:2<291:PYNC-S>2.0.ZU;2-L
Abstract
Reactions of [{NbCl3(dme)}(n)] or [NbCl3(dme)(RC=CR')] with a heterocy cle containing alpha-keto stabilized phosphorus ylide, 2-TCMP = 2-thia zolylcarbonyl}methylene]triphenyphosphorane, allowed the synthesis of the first alpha-keto ylide niobium complexes, [{NbCl3(2-TCMP)}(2)] and [NbCl3(2-TCMP)(RC=CR')] respectively. The new complexes were spectros copically characterized and the X-ray molecular structure for one of t hem was also determined. (C) 1997 Elsevier Science S.A.