C. Ogric et al., ETA(2)-DIMETHYLAMINO(THIO)CARBENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN, Journal of organometallic chemistry, 541(1-2), 1997, pp. 71-75
eta(2)-Dimethylamino(thio)carbene complexes of molybdenum and tungsten
are formed reacting the tricarbonylmetallates of molybdenum and tungs
ten [LM(CO)(3)](-) (L = Cp, eta(5)-C-5(CH3)(4)CH2CH3, HBpz(3), HB(pzMe
(2))(3)) with dimethylthiocarbamoylchloride. The structures of the new
eta(2)-thiocarbene complexes were determined by X-ray diffraction ana
lysis.