SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE HOMOLEPTIC MAGNESIUMBIS ZINCATE COMPLEX MG(THF)(6)[ZN(CH2PH)(3)](2)

Authors
RIJNBERG E JASTRZEBSKI JTBH BOERSMA J KOOIJMAN H SPEK AL VANKOTEN G
Citation
E. Rijnberg et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE HOMOLEPTIC MAGNESIUMBIS ZINCATE COMPLEX MG(THF)(6)[ZN(CH2PH)(3)](2), Journal of organometallic chemistry, 541(1-2), 1997, pp. 181-185
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
541
Issue
1-2
Year of publication
1997
Pages
181 - 185
Database
ISI
SICI code
0022-328X(1997)541:1-2<181:SASCOT>2.0.ZU;2-R
Abstract
The addition of Mg(CH2Ph)(2)(thf)(2) to a thf solution of Zn(CH2Ph)(2) yields the zincate complex Mg(thf)(6)[Zn(CH2Ph)(3)](2) (1), which has been characterized by X-ray crystallography and NMR. Complex 1 is cle aved by tmeda into a 1:2 mixture of Mg(CH2Ph)(2)(tmeda) and Zn(CH2Ph)( 2)(tmeda). (C) 1997 Elsevier Science S.A.