COMPLEXES OF PERHALOGENATED CYCLOPENTADIENES AND ALKYNES .19. STUDIESON THE SYNTHESIS AND REACTIVITY OF CYMANTRENYLALKOXYSILANES [C5X5-N(SIME2OR)(N)]MN(CO)(3) (N = 1, 2, X = CL, BR, H)

Authors
SUNKEL K SCHUBERT S HOFMANN J
Citation
K. Sunkel et al., COMPLEXES OF PERHALOGENATED CYCLOPENTADIENES AND ALKYNES .19. STUDIESON THE SYNTHESIS AND REACTIVITY OF CYMANTRENYLALKOXYSILANES [C5X5-N(SIME2OR)(N)]MN(CO)(3) (N = 1, 2, X = CL, BR, H), Journal of organometallic chemistry, 541(1-2), 1997, pp. 199-206
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
541
Issue
1-2
Year of publication
1997
Pages
199 - 206
Database
ISI
SICI code
0022-328X(1997)541:1-2<199:COPCAA>2.0.ZU;2-R
Abstract
Treatment of the cyclopentadienylsilanes [C5X4(SiMe2H)]Mn(CO)(3) (X=Br , Cl, H) and [C5Br3(SiMe2H)(2)]Mn(CO)(3) with PdCl2 yields the corresp onding chlorosilanes 1a-c and 2. From these and alcohols CnH2n+1OH (n= 1-10) the cymantrenyl-alkoxysilanes [C5X4(SiMe2OR)]Mn(CO)(3) 3-5 and [ C5Br3(SiMe2OR)(2)]Mn(CO)(3) 6 can be obtained. (C) 1997 Elsevier Scien ce S.A.