The Environmental Protection Act has created a growing need for the me
asurement and assessment of trace emissions to the environment. This e
ncompasses three main areas of ground, water and the atmosphere. The n
eed to achieve lower emissions has placed a large burden on analytical
techniques, particularly in the areas of trace analysis to ppb and pp
t levels. Chromatographic techniques ale widely used for assessment an
d measurement of emissions in all th,ee areas. Enhanced detectors usin
g mass spectrometry principles are available to lower detection limits
, but these are expensive. Standard chromatography detectors can be us
ed for trace analysis, but this often leads to extensive sample prepar
ation stages to achieve low detection limits. This paper describes the
techniques developed by Thomas Swan & Company to introduce a cost eff
ective way of lowering detection limits. The approach taken meets both
BATNEEC and BPEO constraints.