F. Pawlak et al., AMORPHOUS DEUTERATED CARBON-FILMS IRRADIATED BY SWIFT HEAVY-IONS - INFRARED MEASUREMENTS AND ION-BEAM ANALYSIS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 131(1-4), 1997, pp. 135-140
Mixed hydrogenated and deuterated amorphous carbon films have been irr
adiated at GANIL in the MeV/amu energy range with an electronic stoppi
ng power varying between 1 keV nm(-1) and 13 keV nm(-1). These films r
oughly contain 10% of hydrogen and 30% of deuterium. Carbon (C), hydro
gen (H) and deuterium (D) contents were determined by Rutherford Backs
cattering Spectrometry (RES) and Elastic Recoil Detection Analysis (ER
DA), The evolution of C-H and C-D bondings content's was determined by
infrared absorption measurements. The main effects due to MeV amu(-1)
ion irradiations are the decrease of C-D bondings content and deuteri
um relative concentration (D/C atomic ratio) as a function of fluence.
A long time after irradiation C-H bondings content and hydrogen relat
ive concentration (H/C atomic ratio) increase, The hydrogen absorption
cross section is equal to the deuterium effusion cross section within
the experimental errors whatever is the physical characterisation (io
n beam analysis or infrared absorption), Moreover, both techniques giv
e the same cross sections. Hence the following interpretation is propo
sed: during irradiation hydrogen and deuterium atoms are ejected from
the ion tracks and afterwards are replaced by hydrogen atoms coming fr
om the ambient air and diffusing inside the irradiated material along
the latent tracks.