HYDROFORMYLATION OF 1-HEXENE IN THE PRESENCE OF RHODIUM COMPLEXES IMMOBILIZED ON POLYORGANOSILOXANES

Authors
KOLESNICHENKO NV TEREKHOVA GV TELESHEV AT ALEKSEEVA EI SLIVINSKY EV
Citation
Nv. Kolesnichenko et al., HYDROFORMYLATION OF 1-HEXENE IN THE PRESENCE OF RHODIUM COMPLEXES IMMOBILIZED ON POLYORGANOSILOXANES, Russian chemical bulletin, 46(6), 1997, pp. 1107-1109
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
6
Year of publication
1997
Pages
1107 - 1109
Database
ISI
SICI code
1066-5285(1997)46:6<1107:HO1ITP>2.0.ZU;2-R
Abstract
It was demonstrated that the catalyst system based on acacRh(CO)(2) an d polyorganosiloxanes exhibits high activity and stability in hydrofor mylation of 1-hexene. The effects of the nature of the oligomer, the r atio of oligomers, and the oligomer : rhodium ratio in the polymer on the synthesis and catalytic properties of the system were studied.