INVESTIGATION OF THE REACTIONS OF PYROCATECHOL DERIVATIVES WITH ALBR3BY NMR-SPECTROSCOPY

Authors
GOLOUNIN AV SOKOLENKO VA SHAKIROV MM
Citation
Av. Golounin et al., INVESTIGATION OF THE REACTIONS OF PYROCATECHOL DERIVATIVES WITH ALBR3BY NMR-SPECTROSCOPY, Russian chemical bulletin, 46(6), 1997, pp. 1110-1112
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
6
Year of publication
1997
Pages
1110 - 1112
Database
ISI
SICI code
1066-5285(1997)46:6<1110:IOTROP>2.0.ZU;2-H
Abstract
Alkylpyrocatechols are dealkylated by AlBr3 in CH2Br2 The formation of stable carbenium ions (tert-butyl, methylcyclopentyl, and 1-adamantyl ) was detected by H-1 NMR spectroscopy. Pyrogallol and 2,3-dihydroxyna phthalene are coordinated with ALBr(3) in the tautomeric keto form, an d 2-mercapto-4-methylphenol forms a complex in the hydroxy form.