F-19 NMR-STUDIES OF THE COMPARATIVE ELECTRONEGATIVITY OF THE PH3E GROUPS (E = C, SI, GE, SN, OR PB) IN PH3E DERIVATIVES OF TRIS(4-FLUOROPHENYL)STANNANETHIOL

Authors
KRAVTSOV DN PEREGUDOV AS KRYLOVA AI GORELIKOVA YY
Citation
Dn. Kravtsov et al., F-19 NMR-STUDIES OF THE COMPARATIVE ELECTRONEGATIVITY OF THE PH3E GROUPS (E = C, SI, GE, SN, OR PB) IN PH3E DERIVATIVES OF TRIS(4-FLUOROPHENYL)STANNANETHIOL, Russian chemical bulletin, 46(6), 1997, pp. 1167-1170
Citations number
31
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
6
Year of publication
1997
Pages
1167 - 1170
Database
ISI
SICI code
1066-5285(1997)46:6<1167:FNOTCE>2.0.ZU;2-8
Abstract
Compounds (4-FC6H4)(3)SnSEPh3 (E = C, Si, Ge, Sn, or Pb) were synthesi zed or generated in solution. The data on the comparative electronegat ivity of the Ph3E groups were obtained from the results of F-19 NMR sp ectroscopy. It was established that, except for E = C, the electronega tivity changes in parallel with the absolute electronegativity of the central atom. Possible reasons for the deviation observed are discusse d.