PHOTOLYSIS OF (ARYLMETHYLSULFANYL)TRIPHENYLPHOSPHONIUM PERCHLORATES -COMPETITIVE PHOTOCLEAVAGE OF SULFUR PHOSPHORUS AND SULFUR CARBON BONDS

Authors
IMRIE C MODRO TA WAGENER CCP
Citation
C. Imrie et al., PHOTOLYSIS OF (ARYLMETHYLSULFANYL)TRIPHENYLPHOSPHONIUM PERCHLORATES -COMPETITIVE PHOTOCLEAVAGE OF SULFUR PHOSPHORUS AND SULFUR CARBON BONDS, Journal of chemical research. Synopses, (6), 1994, pp. 222-223
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
6
Year of publication
1994
Pages
222 - 223
Database
ISI
SICI code
0308-2342(1994):6<222:PO(P->2.0.ZU;2-L
Abstract
(Arylmethylsulfanyl)triphenylphosphonium ions, ArCH2SPPh3+, undergo ph otolysis involving the S-C (major) and S-P (minor) bond cleavage; the former pathway shows negligible substituent effect on the radical vs. ionic products ratio.