Reactions of N-(alpha-benzotriazolylalkyl)-N,N-dialkylamines with the
dialkylamine corresponding to the dialkylamino substituent afford symm
etrical aminals in good yields. Treatment with other dialkylamines giv
es mixtures of the unsymmetrical and the two symmetrical aminals. Cros
s-over experiments of symmetrical aminals demonstrates interconversion
s involving iminium ions and that equilibria exist in the systems.