SYNTHESIS AND CRYSTAL-STRUCTURE OF (O-CH3C6H4NH3)(6)P6O18-CENTER-DOT-2H(2)O

Authors
LARAFA K MAHJOUB A RZAIGUI M DURIF A
Citation
K. Larafa et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF (O-CH3C6H4NH3)(6)P6O18-CENTER-DOT-2H(2)O, European journal of solid state and inorganic chemistry, 34(5), 1997, pp. 481-494
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
European journal of solid state and inorganic chemistry → ACNP
ISSN journal
09924361
Volume
34
Issue
5
Year of publication
1997
Pages
481 - 494
Database
ISI
SICI code
0992-4361(1997)34:5<481:SACO(>2.0.ZU;2-A
Abstract
(o-CH3C6H4NH3)(6)P6O18.2H(2)O is triclinic, P (1) over bar, with Z = 1 and the following unit-cell dimensions: a = 10.395(4), b = 10.793(5), c = 13.839(4)Angstrom alpha = 103.98(3), beta = 91.62(3), gamma = 116 .65(3)degrees Its crystal structure has been determined and refined do wn to R = 0.036, using 5850 independent reflections. Among the three c rystallographically independent CH3-C6H4.NH3 groups one is disordered. All the H-atoms belonging to the non-disordered ligands have been loc ated and refined. The hydrogen-bond distribution is carefully describe d.