MICHAEL MONOADDITION OF NITROMETHANE ON GEM-DIACTIVATED ALKENES IN DRY MEDIA COUPLED WITH MICROWAVE

Citation
D. Michaud et al., MICHAEL MONOADDITION OF NITROMETHANE ON GEM-DIACTIVATED ALKENES IN DRY MEDIA COUPLED WITH MICROWAVE, Tetrahedron letters, 38(43), 1997, pp. 7563-7564
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
38
Issue
43
Year of publication
1997
Pages
7563 - 7564
Database
ISI
SICI code
0040-4039(1997)38:43<7563:MMONOG>2.0.ZU;2-B
Abstract
Nitromethane reacts readily and selectively with a variety of electrop hilic alkenes activated by cyano, ester or amide group to give the cor responding Michael monoadduct within a few minutes, in good yields ove r alumina without solvent and under focused microwaves. (C) 1997 Elsev ier Science Ltd.