TETRAHEDRAL QUADRANIONIC CARBON CLUSTERS

Citation
M. Enlow et al., TETRAHEDRAL QUADRANIONIC CARBON CLUSTERS, Molecular physics, 92(3), 1997, pp. 441-444
Citations number
22
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00268976
Volume
92
Issue
3
Year of publication
1997
Pages
441 - 444
Database
ISI
SICI code
0026-8976(1997)92:3<441:TQCC>2.0.ZU;2-J
Abstract
Ab initio calculations on quadranionic carbon clusters with tetrahedra l symmetry show that the smallest cluster with the formula C-8n+1(4-) that is stable with respect to loss of an electron is C-33(4-). These quadranions have a central carbon that is bound to four identical bran ches that display a pattern of alternating short and long bond lengths . Feynman-Dyson amplitudes for electron detachment from the quadranion s are only slightly concentrated in terminal bond regions of each bran ch.