COMPETITIVE HYDROGENATION OF UNSATURATED-HYDROCARBONS BY HYDROGEN-TRANSFER FROM AMMONIUM FORMATE ON A PALLADIUM CATALYST

Authors
DOBROVOLNA Z CERVENY L
Citation
Z. Dobrovolna et L. Cerveny, COMPETITIVE HYDROGENATION OF UNSATURATED-HYDROCARBONS BY HYDROGEN-TRANSFER FROM AMMONIUM FORMATE ON A PALLADIUM CATALYST, Collection of Czechoslovak Chemical Communications, 62(9), 1997, pp. 1497-1502
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Collection of Czechoslovak Chemical Communications → ACNP
ISSN journal
00100765
Volume
62
Issue
9
Year of publication
1997
Pages
1497 - 1502
Database
ISI
SICI code
0010-0765(1997)62:9<1497:CHOUBH>2.0.ZU;2-N
Abstract
Competitive hydrogenation of alkenes (cyclohexene, hex-1-ene, hept-1-e ne, oct-1-ene) and dienes (octa-1,7-diene, cyclohexa-1,3-diene) was ca rried out by catalytic hydrogen transfer from ammonium formate on pall adium in methanol. The adsorptivity and reactivity of the hydrocarbons decreased in the series: cyclic diene > linear diene > linear 1-alken e > cyclic alkene.