Pb. Lloyd et al., TEMPERATURE-PROGRAMMED DESORPTION STUDY OF THE ADSORPTION AND ABSORPTION OF HYDROGEN ON AND IN CU(111), Applied surface science, 119(3-4), 1997, pp. 267-274
Citations number
40
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical","Materials Science, Coatings & Films
TPD studies of the interaction of atomic hydrogen with Cu(111) as a fu
nction of coverage indicate the formation of chemisorbed and absorbed
species at 98 K. At low coverage a single desorption feature, beta, is
observed at 330 K. This desorption feature has been observed previous
ly and assigned to desorption of chemisorbed surface species with a sa
turation coverage of 0.5 ML. With increasing exposure, two more desorp
tion features, alpha(1) and alpha(2), are observed at 200 and 220 K, r
espectively. The alpha(1) state saturates quickly with a relative popu
lation density of approximately 1/2 that of the beta peak. The alpha(2
) state, however, did not saturate. At higher exposures, desorption fr
om the alpha(2) state was greater than ten times the saturated beta st
ate. The alpha(2) state exhibited zeroth order desorption kinetics wit
h an activation energy for desorption of 8.8 kcal/mol and was attribut
ed to desorption of an absorbed species from the bulk. (C) 1997 Elsevi
er Science B.V.