KINETIC-STUDIES ON THE FORMATION REACTION OF CADMIUM(II) WITH PORPHYRIN AND THE SALT EFFECT

Authors
RUAN WJ ZHU ZA CHEN HW LIN HK SHAO Y YANG XL CHEN RT
Citation
Wj. Ruan et al., KINETIC-STUDIES ON THE FORMATION REACTION OF CADMIUM(II) WITH PORPHYRIN AND THE SALT EFFECT, Gaodeng xuexiao huaxue xuebao, 18(10), 1997, pp. 1669-1674
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
18
Issue
10
Year of publication
1997
Pages
1669 - 1674
Database
ISI
SICI code
0251-0790(1997)18:10<1669:KOTFRO>2.0.ZU;2-E
Abstract
The kinetics of formation reaction of Cd(I) with meso-tetra-meta-tolue ne-porphyrin [H2T(m-CH3)PP] in acetone has been studied by means of st opped-flow method. The proper reaction mechanism was proposed, The eff ects of temperature on the reaction rate were investigated. It was fou nd that k(obs) was reduced with the increase of the ionic strength, th at is, the negative kinetic salt effect was observed. According to Deb ye-Huckel theory and the experimental results a good linear relationsh ip between rate constant and ionic strength was obtained.