A NEW-TYPE OF ALUMOXANE OBTAINED BY CONTROLLED HYDROLYSIS OF N,N-DIALKYLCARBAMATO COMPLEXES OF ALUMINUM - CRYSTAL AND MOLECULAR-STRUCTURE OF [AL-4(MU(3)-O)(2)(O2CNPR2I)(8)]

Authors
ABRAM U DELLAMICO DB CALDERAZZO F KASKEL S LABELLA L MARCHETTI F ROVAI R STRAHLE J
Citation
U. Abram et al., A NEW-TYPE OF ALUMOXANE OBTAINED BY CONTROLLED HYDROLYSIS OF N,N-DIALKYLCARBAMATO COMPLEXES OF ALUMINUM - CRYSTAL AND MOLECULAR-STRUCTURE OF [AL-4(MU(3)-O)(2)(O2CNPR2I)(8)], Chemical communications, (20), 1997, pp. 1941-1942
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
20
Year of publication
1997
Pages
1941 - 1942
Database
ISI
SICI code
1359-7345(1997):20<1941:ANOAOB>2.0.ZU;2-1
Abstract
The aluminium(nr) N,N-diisopropylcarbamato derivative [Al-2(O2CNPr2i)( 6)] undergoes hydrolysis with a stoichiometric amount of water giving the mu(3)-oxo derivative [Al-4(mu(3)-O)(2)(O(2)CNPr(i)2)(8)], which is analytically, spectroscopically and structurally characterized.