A NUCLEOPHILIC NIOBIUM(V) NITRIDE PREPARED BY ISOCYANATE DECARBONYLATION

Authors
FICKES MG ODOM AL CUMMINS CC
Citation
Mg. Fickes et al., A NUCLEOPHILIC NIOBIUM(V) NITRIDE PREPARED BY ISOCYANATE DECARBONYLATION, Chemical communications, (20), 1997, pp. 1993-1994
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
20
Year of publication
1997
Pages
1993 - 1994
Database
ISI
SICI code
1359-7345(1997):20<1993:ANNNPB>2.0.ZU;2-J
Abstract
Carbon monoxide is lost upon sodium amalgam reduction of [(OCN)Nb{N(R) Ar}(3)] [R = C(CD3)(2)CH3, Ar = C6H3Me2-3,5] to give crystallographica lly characterized [Na{NNb[N(R)Ar](3)}](2), a nucleophilic niobium(v) n itride which reacts with ClP(NMe2)(2) and O(SO2CF3)(2) to give P- and S-substituted imido complexes, respectively.