THE REDUCTION OF NB2CL6(TMEDA)(2) BY R2NLI - FORMATION OF A DIAMAGNETIC NIOBIUM(II) CLUSTER WITH SHORT NB-NB TRIPLE BOND AND AMIDE C-N BOND-CLEAVAGE

Authors
TAYEBANI M KASANI A FEGHALI K GAMBAROTTA S BENSIMON C
Citation
M. Tayebani et al., THE REDUCTION OF NB2CL6(TMEDA)(2) BY R2NLI - FORMATION OF A DIAMAGNETIC NIOBIUM(II) CLUSTER WITH SHORT NB-NB TRIPLE BOND AND AMIDE C-N BOND-CLEAVAGE, Chemical communications, (20), 1997, pp. 2001-2002
Citations number
32
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
20
Year of publication
1997
Pages
2001 - 2002
Database
ISI
SICI code
1359-7345(1997):20<2001:TRONBR>2.0.ZU;2-P
Abstract
Reduction of trivalent Nb2Cl6(tmeda)(2) with either lithium diisopropy lamide or n-butyllithium yields a novel Nb-II cluster which performs o xidative addition into the amide C-N bond.