SYNTHESIS OF NOVEL TETRACYCLO[6.3.0.0(2,6).0(3,10)]UNDECANE AND TETRACYCLO[6.4.0.0(2,6).0(3,10)]DODECANE DERIVATIVES

Authors
MARTINS FJC VILJOEN AM VENTER HJ WESSELS PL
Citation
Fjc. Martins et al., SYNTHESIS OF NOVEL TETRACYCLO[6.3.0.0(2,6).0(3,10)]UNDECANE AND TETRACYCLO[6.4.0.0(2,6).0(3,10)]DODECANE DERIVATIVES, Tetrahedron, 53(44), 1997, pp. 14991-14996
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
44
Year of publication
1997
Pages
14991 - 14996
Database
ISI
SICI code
0040-4020(1997)53:44<14991:SONTAT>2.0.ZU;2-L
Abstract
tetracyclo[6.3.0.0(2,6).0(3,10)]undecane-5,9-dione has been synthesise d from entacyclo[6.3.0.0(2,6).0(3,10).0(5,9)]undecan-1-ol by chromium trioxide oxidation. In the same fashion tetracyclo[6.4.0.0(2,6).0(3,10 )]dodecane-5,9-dione was obtained from pentacyclo[6.4.0.0.(2,6).0(5,9) .0(4,12)] dodecan-2-ol. The synthesis of a 4,6-cyclised homologue is a lso discussed. (C) 1997 Elsevier Science Ltd.