Fa. Gianturco et al., INTERACTION ANISOTROPY AND VIBROTATIONAL EXCITATION IN PROTON-SCATTERING FROM N-2((1)SIGMA(+)(G)), The Journal of chemical physics, 107(17), 1997, pp. 6634-6645
Stimulated by the experimentally observed low vibrational inelasticity
and the somewhat stronger rotational inelasticity in the H+-N-2 colli
sions, we present here a quantum dynamics study of the scattering proc
ess in the framework of vibrational close-coupling rotational infinite
-order sudden approximation. We have employed the recently obtained gr
ound-state potential-energy surface of the system from which both rota
tional and vibrational coupling potentials can be obtained. The variou
s computed dynamical attributes such as differential and integral cros
s sections, and average vibrational as well as rotational energy trans
fers, are analyzed in detail and compared successfully with the availa
ble experimental results. (C) 1997 American Institute of Physics. [S00
21-9606(97)02141-7].