REGIO-CHEMICAL AND STEREOCHEMICAL EFFECTS IN THE HYDROBORATION OF DELTA(2)-STEROIDAL ALLYLIC AND HOMOALLYLIC ALCOHOLS

Authors
HANSON JR LIMAN MD NAGARATNAM S
Citation
Jr. Hanson et al., REGIO-CHEMICAL AND STEREOCHEMICAL EFFECTS IN THE HYDROBORATION OF DELTA(2)-STEROIDAL ALLYLIC AND HOMOALLYLIC ALCOHOLS, Journal of chemical research. Synopses, (8), 1997, pp. 282-283
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
8
Year of publication
1997
Pages
282 - 283
Database
ISI
SICI code
0308-2342(1997):8<282:RASEIT>2.0.ZU;2-G
Abstract
A comparison between the hydroboration of Delta(2)-steroidal 1 alpha-a llylic and 5 alpha-homoallylic alcohols reveals that whereas both have a stereochemical directing effect, only the allylic alcohol modifies the regiospecificity of the reaction.