The synthesis of several representatives of the new thieno- and pyrazo
lo[1,2,4]thiadiazine 1,1-dioxides ring systems is described. It was ca
rried out by cyclization of the isocyanates (4) formed in the Curtius
rearrangement of acyl;azides (3). The reactivity of these new rings to
wards some electrophilic reagents was also explored.