PHOTOCHEMICAL BEHAVIOR OF HALOGENOHETEROCYCLIC DERIVATIVES - THE ALTERNATIVE BETWEEN ARYLATION AND DEHALOGENATION REACTIONS

Authors
DAURIA M
Citation
M. Dauria, PHOTOCHEMICAL BEHAVIOR OF HALOGENOHETEROCYCLIC DERIVATIVES - THE ALTERNATIVE BETWEEN ARYLATION AND DEHALOGENATION REACTIONS, Heterocycles, 45(9), 1997, pp. 1775-1780
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
45
Issue
9
Year of publication
1997
Pages
1775 - 1780
Database
ISI
SICI code
0385-5414(1997)45:9<1775:PBOHD->2.0.ZU;2-Q
Abstract
Semiempirical calculations on the transient intermediates involved in the irradiation of halogenoheterocyclic derivatives showed that the di fference between the heat of formation of the substrates and the deat of formation of the radical intermediates derived from the cleavage of the C-X bond can be a useful parameter to justify the observed chemic al behaviour towards the arylation reaction or the dehalogenation reac tion.