In collisions with Arq+ ions (q = 6-11) at 3-10 qkeV we produced SFn+,
2+ molecular ions, n = 1-5. Since even the singly charged SF6+ ion is
unstable all collisions lead to dissociation with a large number of di
ssociation channels. We observed an alternating structure in the mass
spectra of the singly and doubly charged molecular ions SFn+ and SFn2. The cations SFn+ are more stable for an odd number of fluorine atoms
'(n = 3, 5) and the dications SFn2+ are more stable if the number of F
atoms is even (n = 2, 4).