OXYGEN SENSING PROPERTIES OF A NEW RUTHENIUM-(II) COMPOUND

Citation
Ai. Baba et al., OXYGEN SENSING PROPERTIES OF A NEW RUTHENIUM-(II) COMPOUND, Analytical letters, 30(13), 1997, pp. 2289-2299
Citations number
29
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032719
Volume
30
Issue
13
Year of publication
1997
Pages
2289 - 2299
Database
ISI
SICI code
0003-2719(1997)30:13<2289:OSPOAN>2.0.ZU;2-Y
Abstract
The design of efficient oxygen measuring devices has important environ mental, clinical and process control applications. Several methods are available for oxygen quantitation, but those based on the dynamic que nching of luminescence of inorganic compounds have several advantages. In this work the oxygen-quenching luminescence characteristics of a n ewly synthesized ruthenium (II) compound immobilized on an optical fib er was investigated using Stern-Volmer kinetic analysis. Results obtai ned show that the luminescence intensity of the newly synthesized comp ound exhibits a second order dependence on oxygen concentration from 0 -100 %. The oxygen sensing characteristics of this new compound are co mparable to other conventional oxygen sensing compounds.