UNUSUAL SOLVENT EFFECT ON ABSORPTION-SPECTRA OF NONPLANAR DODECAPHENYLPORPHYRINS WITH DIFFERENT SUBSTITUENTS

Authors
LI M XIAO ZD XIANG H LU ZH
Citation
M. Li et al., UNUSUAL SOLVENT EFFECT ON ABSORPTION-SPECTRA OF NONPLANAR DODECAPHENYLPORPHYRINS WITH DIFFERENT SUBSTITUENTS, SPECT ACT A, 53(11), 1997, pp. 1691-1695
Citations number
19
Categorie Soggetti
Spectroscopy
Journal title
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY → ACNP
ISSN journal
13861425
Volume
53
Issue
11
Year of publication
1997
Pages
1691 - 1695
Database
ISI
SICI code
1386-1425(1997)53:11<1691:USEOAO>2.0.ZU;2-Q
Abstract
Ultraviolet absorption spectra of three nonplanar porphyrins possessin g the different substituents were investigated in sixteen solvents. Th e spectral changes were found to be the strong solvent and substituted group dependences. The results can be interpreted in terms of H-bondi ng interactions between the pyrrole NH protons and the lone pair elect rons of the solvent molecules. (C) 1997 Elsevier Science B.V.