SYNTHESIS AND REACTIVITY OF CYCLIC DIENOL-ETHERS

Citation
C. Alexandre et al., SYNTHESIS AND REACTIVITY OF CYCLIC DIENOL-ETHERS, Bulletin de la Societe chimique de France, 134(7), 1997, pp. 719-723
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
ISSN journal
00378968
Volume
134
Issue
7
Year of publication
1997
Pages
719 - 723
Database
ISI
SICI code
0037-8968(1997)134:7<719:SAROCD>2.0.ZU;2-P
Abstract
Several dienes, synthesized from cyclic enol-ethers, were opposed to a lpha-phenyl or alpha-alkyl sulfinylalkenones in Diels-Alder reactions. alpha-Phenylsulfinylalkenones gave unstable adducts which spontaneous ly lost phenylsulfenic acid, while the other dienophiles led to stable adducts in the form of diastereoisomeric mixtures.