Dp. Ertchak et al., THE ORIGIN OF DOMINATING ESR ABSORPTION IN ION-IMPLANTED DIAMOND, Physica status solidi. b, Basic research, 203(2), 1997, pp. 529-547
Detailed ESR studies in diamond single crystals implanted with high-en
ergy ions of copper, neon and nickel have been performed. A new idea o
f the origin of the dominating ESR absorption in implanted diamond sin
gle crystals as conditioned by the resonance absorption by mobile quas
iparticles is confirmed and developed. Mobile quasiparticles are assig
ned tentatively to topological soli tons like to those described by Su
, Schrieffer, Heeger in trans-polyacetylene. The spin waves have been
observed for the first time at room temperature in diamond single crys
tals implanted by high-energy ions. The observed spin waves represent
a new kind of elementary excitations as being produced by the spin sys
tem of mobile quasiparticles (solitons). The Mott-Hubbard metal-insula
tor transition (side by side with that of Peierls) must be taken into
consideration in the explanation of the physical properties of quasi-1
D carbon structures produced in diamond single crystals as a result of
high-energy implantation. The substutional anisotropy of the ESR spec
tra in relation to the magnetic component H-1 of the microwave field a
ccompanied by the appearance of additional lines has been found for th
e first time in implanted diamond single crystals. The given anisotrop
y seems to be determined by the anisotropy of the excitation of quasip
articles including spin wave quanta in track-like quasi-one-dimensiona
l structures of the samples studied.