In this work, pyrotechnic propellants as gas generating agents and the
ir possible application in fire extinguishers are studied. Specific pr
operties of the delivered combustion gases are required: high yield of
gas, low burning temperature, minimal slag production, neither toxic
nor highly reactive combustion products, adequate burning properties,
and easy and reliable ignition. A whole range of gas generating agents
(mixed with an oxidiser) are considered and some theoretical combusti
on properties are calculated. Depending on the application one gas gen
erating agent will be more suitable than another. Further on, we will
focus on the design and the use of a gas generator in portable fire ex
tinguishers for which the production of nitrogen gas or non-toxic and
chemically inert exhaust gases are required. Possible gas generating a
gents for this application are alkali azide based propellants. The inf
luence of SiO2 and MgCO3 on KNO3-NaN3-mixtures is investigated. Propel
lant characteristics are determined by experiments in closed vessel an
d scale rocket engine. The developed propellant and a specifically des
igned combustion chamber have been successfully used for pressurising
portable fire extinguishers.