THE REACTIVITY OF ALCOHOLS AND GLYCOLS IN REACTIONS WITH ALPHA-OXIDES

Authors
GUSKOV AK MAKAROV MG SHVETS VF
Citation
Ak. Guskov et al., THE REACTIVITY OF ALCOHOLS AND GLYCOLS IN REACTIONS WITH ALPHA-OXIDES, Kinetics and catalysis, 38(5), 1997, pp. 603-608
Citations number
5
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
38
Issue
5
Year of publication
1997
Pages
603 - 608
Database
ISI
SICI code
0023-1584(1997)38:5<603:TROAAG>2.0.ZU;2-3
Abstract
The dependence of the reactivity of alcohols and their polyoxyethylate d derivatives with respect to alpha-oxides on the solvability of a med ium is investigated. The ratio of the ether and oxygen groups, which c orrelates with the solvability of the reaction medium, is shown to pla y the crucial role. On the basis of the dependences observed, models m ay be constructed which are applicable for calculating the polyoxyalky lation reactors.