KINETICS AND MECHANISM OF DECOMPOSITION OF THE BETA-AMMONIUM ETHYL COMPLEX OF PT(IV) IN AQUEOUS IODIDE SOLUTIONS

Authors
MITCHENKO SA ZAMASHCHIKOV VV SLINKIN SM
Citation
Sa. Mitchenko et al., KINETICS AND MECHANISM OF DECOMPOSITION OF THE BETA-AMMONIUM ETHYL COMPLEX OF PT(IV) IN AQUEOUS IODIDE SOLUTIONS, Kinetics and catalysis, 38(5), 1997, pp. 609-612
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
38
Issue
5
Year of publication
1997
Pages
609 - 612
Database
ISI
SICI code
0023-1584(1997)38:5<609:KAMODO>2.0.ZU;2-R
Abstract
The stage mechanism of the new decomposition reaction of the beta-ammo nium ethyl complex of platinum(IV) K[Pt(CH2CH2NH3+)Cl-5] with the libe ration of ethylene in the Pt(II)-NaI-H2O-phosphate buffer system at 80 degrees C is studied. The complementary reduction of the beta-ammoniu m ethyl complex of Pt(IV) to the corresponding derivative of Pt(II) is found to precede ethylene evolution.