STRUCTURE OF MO(VI), V(V), AND TI(IV) ALKYLPEROXY AND PEROXY COMPLEXES DEDUCED FROM NMR DATA AND THEIR REACTIVITY

Authors
TALZI EP SHALYAEV KV BABUSHKIN DE SOBOLEV AP
Citation
Ep. Talzi et al., STRUCTURE OF MO(VI), V(V), AND TI(IV) ALKYLPEROXY AND PEROXY COMPLEXES DEDUCED FROM NMR DATA AND THEIR REACTIVITY, Kinetics and catalysis, 38(5), 1997, pp. 619-629
Citations number
39
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
38
Issue
5
Year of publication
1997
Pages
619 - 629
Database
ISI
SICI code
0023-1584(1997)38:5<619:SOMVAT>2.0.ZU;2-F
Abstract
NMR-spectroscopic studies of V-51, (MO)-M-95, Co-59, O-17, and H-1 nuc lei present in coordination compounds that catalyze alkene and alkane oxidation with organic hydroperoxides are reviewed. Multinuclear NMR s pectroscopy was shown to have advantages in structural studies of sele ctive oxidation intermediates.