AMMOXIDATION OF METHYLPYRAZINE OVER BINARY OXIDE SYSTEMS .1. CATALYTIC PROPERTIES OF THE VANADIUM-ANTIMONY SYSTEM

Authors
BONDAREVA VM ANDRUSHKEVICH TV ZENKOVETS GA
Citation
Vm. Bondareva et al., AMMOXIDATION OF METHYLPYRAZINE OVER BINARY OXIDE SYSTEMS .1. CATALYTIC PROPERTIES OF THE VANADIUM-ANTIMONY SYSTEM, Kinetics and catalysis, 38(5), 1997, pp. 657-661
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
38
Issue
5
Year of publication
1997
Pages
657 - 661
Database
ISI
SICI code
0023-1584(1997)38:5<657:AOMOBO>2.0.ZU;2-L
Abstract
Catalytic properties of the vanadium-antimony oxide system in ammoxida tion of methylpyrazine were studied at 230-480 degrees C. Two regions of compositions which differ in both activity and selectivity to the r eaction products were determined: the vanadium-enriched region and tha t enriched by antimony. The catalytic activity increased with increasi ng vanadium content. The maximum yield of pyrazinecarbonitrile was ach ieved on the sample containing 10 mol % V2O5; the minimum yield was fo und for the sample with the equimolar composition.