REACTIONS OF ELECTRON-RICH OLEFINS WITH PROTON-ACTIVE COMPOUNDS

Citation
H. Kucukbay et al., REACTIONS OF ELECTRON-RICH OLEFINS WITH PROTON-ACTIVE COMPOUNDS, Synthetic communications, 27(23), 1997, pp. 4059-4066
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
27
Issue
23
Year of publication
1997
Pages
4059 - 4066
Database
ISI
SICI code
0039-7911(1997)27:23<4059:ROEOWP>2.0.ZU;2-X
Abstract
From the reaction of electron-rich olefins, bis(1,3-dimethylbenzimidaz olidine-2-ylidene), I, or bis(3-methylbenzothiazolidine-2-ylidene), LI with proton active compounds, such as dimethyl phosphite, diethyl pho sphite, acetonitrile and benzaldehyde were obtained 2-substituted benz imidazole or benzothiazole derivatives. The compounds synthesized were identified by H-1, C-13, P-31-NMR, mass, FT-LR spectroscopic techniqu es and micro analysis.